On the basis of existing data it appears that the high-temperature superconductivity above 77 K reported here, occurs only in compound systems consisting of a phase other than the K2NiF4 phase. A narrow superconducting transition was obtained with T sub c0 = 98 K and T sub c1 = 94 K in Y-Ba-Cu-O (YBCO). Preliminary results indicate that YBCO is rather different from the layered LaBCO, LaSCO, and LaCCO. While electron-photon interaction cannot be absent from this compound system, nonconventional enhanced superconducting interactions due to interfaces, Resonating Valence Bond (RVB) states, or even a superconducting state beyond the BCS framework, may be required to account for the high T sub c in YBCO. It is believed that study of the possible subtle correlation between magnetism and superconductivity will definitely provide important insight into the superconducting mechanism in YBCO and other oxides.